The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Due to problems with the server certificate, this web page is currently only available

at https://uvvis.mpch-mainz.gwdg.de but not at https://www.uv-vis-spectral-atlas-mainz.org.

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Alkanes+alkyl radicals / Alkyl radicals / CH3 / Cameron(2002)_298K_216.4nm(max)

DATAFILE: CH3_Cameron(2002)_298K_216.4nm(max).txt
NAME: methyl radical
FORMULA: CH3
AUTHOR(YEAR): Cameron(2002)
T: 298K
λ: 216.4nm(max)
BIBLIOGRAPHY: M. Cameron, V. Sivakumaran, T.J. Dillon, and J.N. Crowley, "Reaction between OH and CH3CHO. Part 1. Primary product yields of CH3 (296 K), CH3CO (296 K), and H (237-296 K)", Phys. Chem. Chem. Phys. 4, 3628-3638 (2002); DOI: 10.1039/B202586H
COMMENTS: Pulsed laser dissociation of Cl2 at 351 nm in the presence of CH4 in N2 bath gas to produce the CH3 radicals, and single-wavelength absorption measurements at 216.4 nm near to the maximum of the absorption spectrum; spectral resolution 0.75 nm

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